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International Journal of Development
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Volume Volume 13 (2024)
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Volume Volume 11 (2022)
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Attia, M., Saad, M., Hassanein, T., Khalil, E., Sheta, S., El-Sheikh, S. (2022). Assessment of Hg2+ in hazardous wastes using chemosensor neutral red dye. International Journal of Development, 11(1), 15-25. doi: 10.21608/idj.2022.281276
Mohamed S. Attia; Mohamed E. Saad; Taha F. Hassanein; Eid Metwally Khalil; Sheta M. Sheta; Said M. El-Sheikh. "Assessment of Hg2+ in hazardous wastes using chemosensor neutral red dye". International Journal of Development, 11, 1, 2022, 15-25. doi: 10.21608/idj.2022.281276
Attia, M., Saad, M., Hassanein, T., Khalil, E., Sheta, S., El-Sheikh, S. (2022). 'Assessment of Hg2+ in hazardous wastes using chemosensor neutral red dye', International Journal of Development, 11(1), pp. 15-25. doi: 10.21608/idj.2022.281276
Attia, M., Saad, M., Hassanein, T., Khalil, E., Sheta, S., El-Sheikh, S. Assessment of Hg2+ in hazardous wastes using chemosensor neutral red dye. International Journal of Development, 2022; 11(1): 15-25. doi: 10.21608/idj.2022.281276

Assessment of Hg2+ in hazardous wastes using chemosensor neutral red dye

Article 2, Volume 11, Issue 1, 2022, Page 15-25  XML PDF (338.62 K)
Document Type: Original Article
DOI: 10.21608/idj.2022.281276
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Authors
Mohamed S. Attia email 1; Mohamed E. Saad2; Taha F. Hassanein2; Eid Metwally Khalil2; Sheta M. Sheta3; Said M. El-Sheikh
1Department of Chemistry, Faculty of Science, Ain Shams University, Cairo, Egypt
2Chemistry Department, Faculty of Science, Helwan University, Cairo, 11795, Egypt
3Inorganic Chemistry Department, National Research Centre, 33 El-Behouth St., Dokki, Giza, 12622, Egypt
Abstract
A new, simple, sensitive and selective spectrofluorimetric method for the determination of trace amounts of Hg2+ in hazardous wastes of fluorescent lamps using chemosensor neutral red dye is developed in acetonitrile at pH 6.6. The Hg2+ can remarkably quench the fluorescence intensity of neutral red dye in acetonitrile at λex = 380 nm. The lowering of fluorescence intensity of neutral red dye is proportional to the concentration of Hg2+ and it is used as optical sensor for its assessment. The dynamic range found for the determination of Hg2+  concentration is 2.3 × 10-9 – 8.0 ×10-6 mol l−1 with a detection limit of 1.0 ×10−11 mol l−1.        
Keywords
Hg2+; Neutral red dye; Optical Sensor; Quenching; Fluorescence Intensity
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